Contacts

VERGE Pierre

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LIGNOBENZ

Lignin-based benzoxazine vitrimers

Inspiration

Project Summary

Transforming renewable biomass into high-performance materials, this project develops next-generation lignin-based vitrimers using benzoxazine chemistry. The resulting polymers combine sustainability, durability, recyclability, and self-healing properties, opening new opportunities for circular materials in coatings, structural applications, and advanced sustainable technologies.

 

People

VERGE Pierre

Sustainable Polymeric and Particulate Materials

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ADJAOUD Antoine

Sustainable Polymeric and Particulate Materials

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Publications

Elucidating the thermal and polymerization behaviours of benzoxazines from lignin derivatives

A. Trejo-Machin, A. Adjaoud, L. Puchot, R. Dieden, and P. Verge

<p>European Polymer Journal, vol. 124, art. no. 109468, 2020</p>

Deciphering the Self-Catalytic Mechanisms of Polymerization and Transesterification in Polybenzoxazine Vitrimers

Adjaoud A., Marcolini B., Dieden R., Puchot L., Verge P.

Journal of the American Chemical Society, vol. 146, n° 19, pp. 13367-13376, 2024

High-Tgand Degradable Isosorbide-Based Polybenzoxazine Vitrimer

Adjaoud A., Puchot L., Verge P.

ACS Sustainable Chemistry and Engineering, vol. 10, n° 1, pp. 594-602, 2022

Polybenzoxazine-based covalent adaptable networks: A mini-review

Adjaoud A., Puchot L., Verge P.

Polymer, vol. 287, art. no. 126426, 2023

Phloretic acid as an alternative to the phenolation of aliphatic hydroxyls for the elaboration of polybenzoxazine

A. Trejo-Machin, P. Verge, L. Puchot, and R. Quintana

Green Chemistry, vol. 19, no. 21, pp. 5065-5073, 2017

Polybenzoxazines: A sustainable platform for the design of fast responsive and catalyst-free vitrimers based on trans-esterification exchanges

Adjaoud A., Trejo-Machin A., Puchot L., Verge P.

Polymer Chemistry, vol. 12, n° 22, pp. 3276-3289, 2021

Lignin-based benzoxazines: A tunable key-precursor for the design of hydrophobic coatings, fire resistant materials and catalyst-free vitrimers

Adjaoud A., Puchot L., Federico C.E., Das R., Verge P.

Chemical Engineering Journal, vol. 453, art. no. 139895, 2023

Lignin-derived thermosets and vitrimers: Bridging the gap between renewable and recyclable materials

Adjaoud A., Brosse N., Verge P.

Materials Today Chemistry, vol. 42, art. no. 102342, 2024

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